Molex connectors provide a +12 volt rail (yellow), a +5 volt rail (red) and two reference grounds (black). 6 pin PCIe connectors provide 3 +12 volt rails (yellow) and 3 reference grounds (black). Since PCIe connectors don't provide a 5 volt rail it's not possible to convert them back into a full Molex connector. However, since fans only utilize the 12 volt rail, it's possible to tap some fan connectors or a partial Molex connector from it, but I'm not aware of any adapters that do so.