I'm not sure about the OEMs and the PSUs they put in their machines. They have a habit of using whichever vendor they get the best contract with at the time. But if you have an 875W PSU with 4 power cables, you are probably OK. Since you'll have to dig them out of their hiding spot eventually if you are going to add a 2nd card, might as well do it before you order the card... to be sure.
The CPU you can use is dependent upon the socket the MB has, as well as chipset, BIOS, etc. If that board in the link is like yours, you have an LGA 1366 socket. The only processors it will support are:
Intel Core i7 (9xx series)
Intel Xeon (35xx, 36xx,
55xx, 56xx series)
Intel Celeron P1053
Newer (and older) Intel processors are out of the question with that board. Which i7 CPU do you have?