Tough call, but inclined to say not worth it. The recomendation to go 2 x 4 is valid.
1) going from 4 -> 6 gigs will improve multitasking performance, but ONLY if you are bumping the need for more than 4 gigs. Could try this:
... Your page file (virtual memory) is probably set to about 1 gigs. Reduce it to say 1024 mb (1 gig). NOTE: set Min and Max both to 1024! If you do not see any "out of memory errors" then going to 6 gigs probably will not provide any real term performance gaint.
2) You are currently using daul channel, which requires two modules of the same size. By going to a 2 x 4 configuration you will drop back to single channel performance - slight decrease. The diff in real life performance between single and daul channel is not as great as it use to be, but still some.
3) Laptops have limited bios capabilities. Also laptops seem to be much more touchy with ram compatabilities than desktops where you can adjust memory parameters. At the least, must select ram that has the same ratings as the one ram model installed, ie voltage and CL values.
.. Can download and run CPU-z and click on Memory (shows what ram is running @)and SPD ( Shows what specs re stored in Ram Module) tabs.
2 x 4 would allow you to stay in daul hannel mode and provide better multitasking. Side beenie is that you can reduce page file to 1024mbs - NOTE: set Min and Max both to 1024!
CPU-Z :
http://www.cpuid.com/softwares/cpu-z.html
Change virtual memory: http://windows.microsoft.com/en-us/windows7/change-the-size-of-virtual-memory