That won't work in the least.
RAID 1 (mirror) - 1TB + 2TB + RAID 1 = a 1TB RAID array.
The size of the smallest drive.
And RAID 1 is not a backup. Yes, it mirrors data across two drives. It also mirrors accidental file deletions, malware, corruptions. It just does it twice.
What you really need to do is, once you have stuff installed where it needs to be, create an image of that drive. Save it on the 2TB drive. Update once a month or so.
For changeable data (your personal stuff - docs/pictures/etc), there are several easy applications that will take a source and target folder, and on schedule, copy whatever is new or changed over to the target.
SyncBack Free does this easily.
This means that the data (the only really important part) exists in more than one place. OS and applications can be easily recreated. Your personal data cannot.
My current process is this:
Every 12 hours, my designated data folders are copied to another internal HDD
Every 24 hours, those same folders are copied to another PC (external drive on that)
All automated.
So I have 3 copies. The live one, the copy on another internal, and a daily copy on that other drive. My main PC could melt into a pile of goo, and pics of my grandson are still safe.
I don't care about the applications. I have all the serial numbers and install files and disks, etc, and they can always just be reinstalled.