H80i fans are installed in a Push/Pull intake configuration, and in "Performance" mode through Corsair Link. Clocks are at 4.2GHz and 1.180V/Core. It was stress tested using RealTemp and Prime95 running a Small FFTs benchmarking test. Maximum temperatures reached ~80-81c for cores one, two and three; core four is always about ~10c cooler than the other cores (For some odd reason). Ambient temps are anywhere between 32-40c for light loads.
Just some numbers to go by. You might be able to pull better numbers than I've currently got, but for the moment it should give you an idea of what to expect. Keep in mind that you won't see high temperatures just browsing, playing games or what have you. I don't top ~60-65c usually on a day to day basis. Rather they only get that hot when I'm stress testing the CPU to verify stability.
As for overclocking, you should be able to get a clean 4.0GHz overclock without adjusting many, if any, voltages. Even then you'd probably be able to squeeze 4.2GHz without much fuss. 4.4 - 4.5GHz might be a task though.