King Mustard :
I have done the Power Supply Calculator and it shows around 650W, so I'm sure 750W will be enough.
Apart from 750W+, what else should I be looking for?
I keep hearing about rails or something.
Hi - The calculators are OK as a general idea, but almost all of them build in a lot of xtra headroom.
Can't blame them as there are a lot of PSU's out there that can't/don't deliver their rated power specs. Yes,
they outright lie about their performance.
However, a good quality modern design 650w PSU is more than enough for your system. A 750 will do no harm
except to your wallet, but is unnecessary for your build.
Yes, you need to pay particular attention to the +12v rail(s) available amps as the most power hungry components
such as the CPU & GPU(s) draw their current from the +12v rail(s).
If you post your PSU budget & location we could offer some suggestions. Or stick with known to be good
brands such as Seasonic, XFX, Antec, most (but not all) Corsair's, many Silverstone, Enermax, Rosewill Capstone, Tachyion, Fortress series, and some others.
A good rule of thumb, if it seems too good to be true, it is.