Your chip may or may not hit the same speeds as others. But I was able to get to 4.950GHz max stable with the exact same CPU and motherboard. I settled on 4.8375GHz at 1.4375v core with LLC on extreme for my final settings. Note: I was using a Corsair H110 liquid cooler, so you will not hit this high on a Hyper 212 EVO. But this CPU has a lot of potential. I hit 4.5GHz stable at just 1.35v core and LLC on medium. Temps were VERY low.
To answer your questions on what is safe: For a 24x7 overclock, stay below 1.475v core and 55c under stress testing loads. Medium or Extreme LLC will add a little voltage under load and you want some room for fluctuation.
I have been doing this for 10+ years. Prime 95 is good for telling you which cores are weak, but not much else. I recommend using AMD Overdrive or OCCT instead.
I take a 3-step approach:
1) I do a 15-30 minute quick test while tweaking settings to get my numbers close to stable. This stresses and heats the CPU, VRU and chipsets for a quick check to make sure things are staying within safe margins.
2) When getting close to my goal, I do a 1 hour test to confirm short term stability.
3) Once I'm happy with what I believe will be my final settings, I do an 8 hour stress test to confirm my final settings are good.
I've used this method for the last 12 builds I've done. Only 2 have needed a small voltage bump after the 1 hour test to pass the 8 hour test. You can test for longer if you like, but honestly it isn't necessary and a 24 hour test isn't safe unless you're going to stay up all night and babysit it. None of my builds have had any hardware instability issues pop up after the fact.
Make sure ALL of your powersave settings are OFF in the BIOS and your CPU fan is set to PWM with the ramp-up value somewhere in the middle of the scale. Don't use the silent setting on an AIR cooler.
Keep your HT, NB and RAM speeds at or below stock when tweaking the CPU.
Remember to give your NB, HT and RAM voltages a small bump when you OC them, as FSB speed affects more than just the CPU.
Here is a very good guide that I've been using with great success for 4 of my recent FX builds and even an old Phenom II x6 rebuild:
http://www.overclock.net/t/1140459/bulldozer-overclocking-guide-performance-scaling-charts-max-ocs-ln2-results-coming
My final settings:
FSB = 225
HT = x12 for 2700 @ 1.25v (* Stock multi, voltage bumped up)
NB = x11 for 2475 @ 1.150v (* Stock multi, voltage bumped up)
RAM = x8 for 1800 @ 1.53v (* DDR3 1600 @ 1800 needed small voltage bump but timings stayed stock)
CPU = x21.5 for 4.8375 @ 1.4375v
CPU NB Core = 1.2875v (* CPU IMC voltage bump needed when you OC RAM. Helps with stability a lot.)