The splitter you have shown is to be used with a PSU with 8pin PCIe cable with a card with requires 2 ×6pin PCIe connector. That way the card gets 150W from PCIe connector and 75W from PCIe slot on motherboard. You shouldn't use that splitter on a card with 6+8 pin PCIe connectorss since that card can require upto 300W power but that splitter will only be able to provide 150W power + 75W from PCIe slot
If you have two 6pin PCIe cable then you will need to use 4pin molex to 8pin PCIe connector + 6pin PCIe connector which your PSU already has to sufficiently power R9 290x
Here's the converter you'll need
http://www.kenable.co.uk/images/k-pcie-molex_main.jpg
Hope it helps
Edit :Your PSU has 6pin+8pin PCIe cable, which is exactly what you need to power r9 290x.
You need to use both 6pin+8pin PCIe cable which your PSU has with r9 290x.
You don't need any converter or splitter.
And just to make things clear the 8pin PCIe cable can also be used as 6pin PCIe cable by not plugging 2pin connector which is attached alongwith 8pin PCIe cable or 6+2pin PCIe cable
Just use the 6+8pin PCIe cables on your PSU, plug them into 6pin and 8pin connector on R9 290x and you'r good to go