There's a good explanation of the different standards
here. It's a little out of date (the second generation ac routers are now hitting the market, with even higher speeds) but gives a good general overview.
The key differences between wireless n and wireless ac are:
- broader band (which is better for e.g. HD streaming)
- speed
- range (helped by beamforming, whereby the router focuses the signal on the receiver, instead of just broadcasting over a wider area)
There is also a difference between ac routers. Ones like the
Asus RT-AC68u are second generation and support faster speeds than first generation ones. You need to do your research if this is the way you want to go!
In a nutshell, wireless ac is superior to wireless n and should be a consideration if you do a lot of HD streaming or are looking for ultimate speed. But be aware, unless you have a very fast internet connection or do a lot of internal file transfers between computers in your network, you won't see an awful lot of difference in day to day use. And of course if your PCs are wired you will see no benefit whatsoever! You also have to ensure that your existing equipment supports the 802.11ac standard. As it's very new only the latest stuff will, and even then not everything. You can of course get ac adapters for computers but it all adds to the cost. If you want to future proof as much as possible than wireless ac should be on your list, particularly 2nd generation. But as with everything new it will be comparatively more expensive and you need to judge whether your usage requirements require it. There's no point buying a Ferrari if you only ever pop down to the local shop a mile away. It's just extra performance you won't ever use.