NFI.EXE appears to be a CLI tool, not a GUI tool. If so, then you would need to execute it within a CMD window. What appears to be happening now is that the CMD window opens for a brief second, during which time it executes NFI.EXE and then closes.
As for your Toshiba drive, it is reporting that it has reallocated 5 sectors. A drive is deemed to have failed when the Normalised (Current) value of a critical attribute falls below its Threshold. In your case the Current value of 100 is still above the Threshold of 50. You can think of the Raw value as an actual error count, whereas the Normalised values are more like health scores. For example, a drive with 0 bad sectors might receive a health score of 100. As it develops bad sectors, this health score falls. For example, 200 bad sectors might reduce the health score to 80. When the health drops below the threshold, then the drive is deemed to have failed.