To be a little more clear on the answer legend provided, multi GPU performance is based on two things only.
1. The card itself, some cards support multi GPU configurartions and scale up in performance in these situations better than others, for instance the GTX 770 (% of 2nd GPU leveraged) works better in SLI than two Titans.
2. The number of available lanes your CPU and Motherboard Support, Socket 2011 currently has the most lanes available and to my knowledge is the only one to support two GPU's at x16, most socket 1150 motherboards run one GPU a x16 and one at x8, or three at x16 x4 x4, etc.