Positive pressure minimizes hot spots in a case. Static pressure is important too. Having a negative pressure can reduce air flow in the corners of the case, where the path of air does not directly pass over.
In mechanical engineering, engineers typically want a slightly positive pressure to ensure air circulation in public buildings so people can breath fresh air.
Similarly, I believe cases should have more intake than exhaust - so more fresh air is being forced in than sucked out.
It's a bit more complicated than that, but hopefully you can see the relation. Most modern case designers will include 2 intake fans, and one exhaust for the same reason - to ensure good airflow with a slightly positive pressure.