No, it's not possible. A RAID-10 array requires a minimum of 4 drives.
Best to use one of your 2TB drives as a backup drive.
So your RAID-0 array will be your "C" drive, a 2TB drive can be your storage/data "D" drive, and your other 2TB drive will be your "E" drive, which backs up data that's on C & D.
Connect only your 2 SSDs to the first two SATA ports on your motherboard and then create your RAID-0 array.
After you install your O/S on your RAID-0 array you can then connect the other 2 HDDs.
Also FYI, you will only see benchmark speed improvements with 2 128GB SSDs in RAID-0; you won't be able to notice any real-world improvement.