Malefic Grindylow :
I'm just upgrading my parts, could they still authorise it?
Depends on how many times your key has already been activated and the mood of the person on the activation line --- technically the OEM license is tied to the original MOBO that the OS is installed on so changing the MOBO would require purchasing a new license - however MS is pretty lax for the home user market and will usually allow the license to be migrated for a home user unless that key has been activated several times already - Also it never hurts to try it (figure worse case it fails to activate and you have to purchase a new copy within the 30 day trial period (MS allows use for 30 days without activating and only requires the akey be put in prior to that 30 days expiring so would not require reinstalling again)
Best bet would be to try the upgrade and use Phone activation after getting everything setup. At that point one of 2 things will happen -
1.) the phone activation will authorize (if the key has not been activated too many times already in the past several months) and the comupterized phone activation will give you a response code to enter and it will activate and your fine.
or
2.) the activation will fail in which case you will be connected to an actual person that you can explain the reason for reactivating (ie. MOBO failed requiring a new purchase) and depending on your answers to a few questions (ie. is this key being used on any other systems, etc.) the support person will either explain you need to purchase a new license (technically what should happen) or will give you a response code to type in and activate the license you have based on the info on your screen.
In my experience as long as you are friendly and explain the situation to the person on the phone they will usually supply a working response code (figure they are mainly trying to keep pirated versions from being activated 1000s of times not trying to keep a single user from using a key they paid for on another system from being reactivated after an upgrade) - If it doesn't get activated and the person insists a new key be purchased you can then either purchase a new license and use it to activate ( can order a new license online or at a store) once you receive the product just change the key to the new key and run the activation again. Or you can hang up and try again and hope you get a more flexible CS agent on the next try (chances are slim you'd get the same person and each has their own method of deciding whether to give you a new key or making you purchase one so there is no fast and hard rules whether they give you a new key)
So in the end there is nothing to lose by trying to reuse the old license key as the worst case you wind up purchasing a new one within 30 days and best case it activates without problem and you save the $$.