CPU Ring voltage is like VCore for Uncore. Performance gains from overclocking uncore are tiny, I wouldn't bother with it much.
System Agent Voltage is the voltage for things like the integrated memory controller. Upping it a bit can help stabilize high speed RAM and a few other things, none of which are significant for day-to-day overclocking.
Basically, if you just want to get a basic OC going there's no need to mess with these voltages.