to do this you will have to have 2 nic's on the main pc. one that brings in the internet connection and a second that goes to the other pc. then enable internet connection sharing and it will walk you through the rest.
if you don't already have all the needed cards and such, the usb wifi dongle suggested above is so much a better and easier way to make it happen. they run about $30 or more and work very well. i have actually done this in the past way back in the day and it was a huge pain in the @55 especially if you need to port forward or anythign like that to the second pc. many steps to get this done with connection sharing as each nic acts as an acces point which has to be configured as you go down the line.
do yourself a favor and just get a wifi dongle