bzand :
if the PSU has two 12V rails it might be a problem
what are rails? Are they how many diffrent sets of chains come out of the psu? Like how some have one but most have two? If that is it would the diffrence not exist if only one of the two plugs on the chain is used?
Not necessarily. Rails are how many different circuits or branches the +12V line is divided up into. It might be reflected in the various power daisy chains, it might not. Generally, 2 x rails mean the board gets one and everything else gets the other. It could be split along the aux power chains too. The GPU's PCIe connectors could be on their own rail. It varies by manufacturer.
Single rail PSUs of course, run everything off a common +12V "branch".
You'll notice that the SATA power daisy chain has smaller gauge wire (thinner) than the ones on the Molex daisy chain. Not designed to carry the amount of current. Oh wait, you said you don't have a Molex daisy chain. What kind of computer PSU has no Molex connectors?