Selecting Best Answers is a privilege, left to the originators of a thread. You have the ability to select Best Answers because you've received five Best Answers yourself. However, there are rules for this (and we know, they're not clearly laid out).
1) Under no circumstance are you to select the Best Answer in an active thread you did not originate (active meaning answers within the past two months).
2) If the original poster of the thread has selected a Best Answer, under no circumstance are you to change that selection.
3) If a Best Answer has been selected by a member of Tom's Hardware and is clearly wrong, you may then select the correct Best Answer.
4) If the original poster of a thread has clearly marked an incorrect Best Answer, see rule #2.
I think that covers everything. For the most part, we recommend that you simply ignore the feature (except in threads you've started).