Well the external eSATA ports are certainly interesting, and they are at SATA III speeds.
Fairly slow for a PCIe SSD though. Even in 2008/2009 you could get OCZ revo drives that broke 1000MB/s. Late model NVMe drives are pushing 2000MB/s through PCIe 3.0/PCIe M.2 slots.
Your internal controller only supports up to SATA II, so a SATA SSD upgrade wouldn't be that impressive.
They do list boot support, so it would give some pep to your aging machine. Wouldn't fit into the trashcan Mac Pros though, so this would be a $600 purchase that couldn't be re-used.
In looking at available alternatives, there is no guarantee that you could boot from some of the later models. Still some Revodrives out there, but they would be quite old at this point, and about the same cost.
Some reports of success with the Intel 750, but it won't boot without a UEFI bios, which I don't think the 2009 mac pro has.