When you press the power button, does nothing happen at all? No fans or disks spinning? Are any LEDs lit anywhere? I don't know your specific motherboard, but many have an LED that lights when standby power is applied, i.e., PSU plugged in and switched on, but PC is not running. Are there any indications of life anywhere in your system? Or is it absolutely, totally dead?
There are plenty of threads on Tom's that cover 'system won't POST / boot', etc. Have you looked at those? There is a great deal of excellent information there. The first place to start is the PSU - does it start up if you disconnect all loads, and connect the green wire to any adjacent black wire? Do you have (or can you borrow) a cheap PSU tester?