ajpaolello :
I'm actually curious how that could be the case if someone would like to explain because logically it doesn't to me. The heatsink of a CPU and GPU are what pull heat away from the silicon. All power does is give the card or chip power to work. So in theory it should be a smaller PSU that makes them cooler because less wattage less work they can do and less heat output. But realistically that makes no sense.
A PSU will only provide what is needed, and no more, so in the example of the 300 and 500w PSUs they will both provide perhaps 250w.
However the 300w PSU will be nearer the limit and be less efficient, whilst the 500w will be in it's sweet spot. Poor efficiency is the cause of heat.
Also the 500w will have better heat sinks and fans and be able to manage that great better.