Well, just had quite the scare. Tried to manually change a couple other voltage-related settings, in case that was what was causing the voltage spikes.
PC didn't boot... not even to POST.
For some reason the CMOS reset button at the back of my motherboard didn't have any effect - that led me to all kinds of terrifying conclusions; 'did I fry my CPU?', 'did I fry my RAM?', 'did I fry my motherboard?'. Fortunately, I noticed another CMOS reset button inside the case, near the USB headers. Hitting that caused my PC to power on, then a couple seconds later power off again. After another couple seconds of being off, it powered itself on again and booted to BIOS.
PHEW!
I put all the BIOS settings back to how they were before, and rebooted. It would appear that inexplicably there're a few lasting effects, however - for some reason, my PC seems to take twice as long to boot as it should usually, with quite noticable unresponsiveness for the first 5-10 seconds. My OS is located on an SSD - A Samsung 850 EVO, 500 GB to be precise.
Before this whole affair, it booted in half the time, with virtually no unresponsiveness (~1-2 seconds) upon first login. I couldn't think how this could've occurred. Perhaps relevant, is that the first time it booted an error was thrown about RAID configurations, despite the fact that I am not using any RAID configuration. I should note that both my drives (SSD main/OS drive, and HDD storage drive) are recognised seperately and are functioning normally, apart from the fact that the SSD seems slower somehow.
Welp. Quite enough adrenaline for one morning.