Ok quite a few things you need to do.
To use a RAID 0 on a OS drive you MUST have a hardware RAID. If you don't know if your motherboard does it or not post what your motherboard make is here.
ALSO! If one drive failes YOU WILL LOSE ALL FILES ON THAT RAID 0! SO HAVE A BACKUP! A lot of people are just like DON"T DO IT! Me I have nothing but RAID 0's but i have backups though.
First thing is follow the directions for converting to use to RAID here
http://www.overclock.net/t/1227636/how-to-change-sata-modes-after-windows-installation
reboot your PC and make sure it boots.
Then download and install Macirum Reflect. it is free. Make the rescue CD or a USB boot drive. Set aside.
Reboot the PC and go into the BIOS. Change of AHCI to RAID. Make sure your PC boots. If not go back and reset back to AHCI and check the registry settings.
If the PC boots go and use macrium reflect to make a backup to one of your other drives. Once the backup is done (I would verify it just to make sure the image is good) you want to turn off the PC. disconnect ALL drives but the 2 SSDs. When you start up there should be the option to enter the RAID configuations utility. Go though and make a RAID 0 of the two SSDs.
Turn off the PC, reconnect the hard drive. Go into the BIOS and set the RAID to the primary boot drive. Now boot from that rescue media.
Once loaded click on the restore tab, browse for an image, find your image you made, and then restore it to the new 1TB RAID 0. Once that is done restart your PC and you should be good! You may have to go in and expand the partition to get the rest of the space.