Kabar74 :
Hmmm ..which is more accurate?....AI Suite 3 (Asus app) shows around 46C...Core Temp shows avg 10C more during Prime95 test.
Just go with whichever is higher... but you're entirely safe on those temps anyway, so nothing to worry about.
I assume you haven't raised the voltages yet? That's what really has an impact on temps.
OCing 101
Frequency (=speed) you want as high as possible
Voltage you want as low as possible (this is what really impacts power draw and heat).
As you raise the frequency at some point the system will become unstable, you'll get errors, BSODs, lockups, etc. That's because the transistors in the chip can't change state quickly enough to match the CPU frequency. Raising the voltage forces the transistors to change state faster, thus keeping the CPU stable at higher frequencies, but at the cost of additional power draw and heat.
So stress testing at every point, you keep raising the frequency until things get unstable. Then raise voltage. Once stable, you can return to raising frequency again. As you stress test you monitor temps to make sure they stay under control. And set yourself a voltage limit (people will argue anywhere from 1.25 to 1.45... I'd be surprised if you can get much over 1.3-1.35 with your cooling).