OK, I can suggest ways to get all your fans under mobo automatic control. This will deal with your case ventilation fans only. At the end I'll ask for more info on your liquid cooler.
The starting point is fan type. All four of the fans supplied with your case are of the 3-pin design. I'm guessing the fifth fan you added also is. Now the manual on your mobo, on p. 13, shows labels on the three SYS_FAN headers that say the all have 4 pins BUT only operate in 3-pin Voltage Control Mode. That is just fine for your situation - you have only 3-pin fans and they need that control system. HOWEVER, that means that you can NOT use the Fan Hub supplied with your case, because there is no source (other than the CPU_FAN header) of a PWM signal. And, as you have said, that source is not well suited to controlling your case fans. So, you will need to use a SPLITTER to allow you to connect more than one fan to a mobo header. The limit on this arrangement is simply that the total current load on each SYS_FAN header cannot exceed 1.0 amps. The fans supplied with your case are spec'd at 0.16 amps each, so you could easily connect several of them to one SYS_FAN header and not have a problem.
In selecting a SPLITTER, note how to differentiate them from Hubs. A Splitter has one arm with a female fan connector to plug into the mobo header. Then it has two or three output arms, each with a male (with pins) connector to plug your fans into. It has no other arms. All of the power for the fans comes from the mobo header used. You have a Hub included with your system that looks like a circuit board. But there also are Hubs sold that look like groups of wire arms, similar to a Splitter. These have one extra arm compared to a Splitter, and that arm must plug into a PSU power output (either a 4-pin Molex or a SATA Power Output). A Hub gets power for all its fans from the PSU, BUT it can only work if given a PWM signal from the mobo host header. You cannot arrange that, so a Hub is not suited to your application.
We also have the "positive pressure" aim to work with. I suggest this arrangement. Buy three Splitters with two output arms each, like this:
http://www.newegg.com/Product/Product.aspx?Item=N82E16812423168&cm_re=Fan_Splitter-_-12-423-168-_-Product
Then "stack" them by plugging two of them into the output arms of the third. This makes a compound splitter with four outputs from one mobo header. Put tape around the pins of one of those so they don't short out to anything. Now use that to plug your three front intake fans into one of your mobo's SYS_FAN headers. This puts all three of them under the control of one mobo header. Next, connect each of the other two - the top and rear exhaust fans - to the other mobo SYS_FAN headers. That gets all five of them under mobo control at all times.
Now the balance question. You have three intake fans, two exhaust fans, PLUS two more exhaust fans attached to the CPU cooling system radiator. Moreover, most intake fans have filters in front of them to prevent dust intake, and these restrict the fan capacity a bit. Net result is more exhaust than intake. You could try this to improve balance. Simply disconnect the top exhaust fan - the one that is NOT on the radiator. Now you'll have a matched number of intakes and exhausts, and it MAY be close to balance. Check MOTHERBOARD (not CPU) temperatures before and after you do this, and assure yourself you still have adequate case cooling.
Now on to the liquid cooler system. Exactly what make and model do you have? With that info we can look up its manual and advise how best to connect it to your mobo.