Tolis_GR :
No my bad. I thought you have 2 slots. So put the 2x2 gb to slots of the same color (i.e 1st and 3rd or 2nd and 4th slot). Add your 4 gb to any other slot so you have totally 8 gb of ram which is sufficient for most tasks.
Now you must check what is the rated frequency of your rams. If you have a ram with 1333 mhz, then all of your faster rams will downclock to this frequency.
For example if your 4gb is slower than the 2x2 gb rams, you will be operating with the frequency of your 4gb and vice versa.
So if your remaining 1gb of ram is even slower than any other, just leave it and stay with 4+2+2. Otherwise add your 1 gb. As i said maybe these rams cannot work with each other so you have to check it yourself.
Find the frequencies of your ram and i would explain.
I currently have the 2 2gb stick and the 4gb stick installed, first time I added the 4gb one, pc wouldn't launch, haven't heard (about pairing before), but was fine since my second try.
The 4gb one is 1600MHz, and using task managed, I figured the stock ones are 1333MHz.
Now, for the annoying part, each of those 1gb sticks has different manufacturers, so I'll write here the longest and most comprehensible string of numbers and letters from each one:
Kingston: KVR400X64C3A/1G
Samsung: 1GB 1Rx8 PC2 - 6400U - 666 - 12 - ZZ
Adata: DDR 400(3) 1GX16 U-DIMM