All that aside, the answer is no, it won't work. In a dual rail psu, (98% of them) both rails are actually tied together. A 750ti generally has @60w draw with a minimum requirement of a psu 18A at 12v. At a combined total of 264w on 12v, in an off brand psu, at best you'll be looking at about 150w of safe usage.
https://youtu.be/f6snWfd1v7M
Just because a manufacturer makes claims, unless its a known quality unit that's been thoroughly tested, you can figure anything over half as being dangerously close to needing a fire extinguisher. Pretty much you'll be close to running maximum output of the psu with anything more than simple windows usage.
Don't get 80+ efficiency ratings confused. If a psu says it's 70%efficient, at 300w max that would mean it'll actually pull 430w from the wall, the remaining 30% being wasted as heat.
Also rail count is rather unimportant in almost all cases, the only real difference being that multiple rail psus use smaller components per rail, but generally have higher current tolerances per rail, vrs a single rail that uses very high rated components. The rails are just run in parallel, all joined together at output. There's very, very few psus that have dedicated rails and normally these will be labeled cpu, mobo and accessories, pcie etc.