When you are buying a brand new set, you always buy a matched set of 2x4, or 2x16gb's. You don't buy a separate 4gb or 8gb stick twice. That being said, I'd say there is a good chance that you can run an identical stick of ram with your current one in dual-channel. It's just not guaranteed. For example, me an my wife each bought a set of 2x4gb ram for a total of 8gb. Recently I bought her a new 2x8gb set to replace hers, and I stuck her 2 stick into my system for 4x4gb's. She only has 2 ram sockets. My pc works just fine dual channel using the full 16gb's. However, it is not guaranteed to work in dual channel.
At this time though, I'd save up a bit more and just go ahead and buy a 2x 8gb set. The prices are pretty good, and...