As kaptainkuftic says, most Intel chips throttle at 100c, which is Tjunction max. You may see a specification "Tcase" - this is not core temperature, and not useful to you. Tcase specifies the maximum temperature at the top and center of the CPU's heatspreader, and there's no sensor there. I can only imagine it to be a useful number to a company designing a heatsink or cooling system.
Generally speaking, as long as you stay below Tjmax (100c for most) you'll be alright. Staying further away will improve longevity, but whether that really matters is debatable, since the lifespan of most CPUs is measured in decades, and they almost always become obsolete before they die, even when abused or run in harsh environments.
Forum moderator "CompuTronix" has a temperature guide stickied at the top of this forum which might be useful to you. I consider his recommendations to be rather conservative, but if you follow his advice, you'll definitely be safe.