Not sure if you've encountered this or not or are aware of...
Some programs, such as AV/Maleware and even certain APP center types for motherboard monitoring/OC utility (just as an example) while running, can sometimes interfere with NV Control Panel being able to enable SLI.
However, you will usually/should receive a prompt, when this is the case. You made no mention, so prob a non-issue but just throwing it out there in any event.
EDIT: If this where the case, you'd only need to disable whichever program causing the issue, then enable SLI, then restart the disabled program.