How much OC do you have? I have not upped my voltage at all and run a +150 on the base clock (I cant remember the memory). Even when I bump up my voltage I cant get a stable clock past 160. I am running SLI and I think one of my cards was a lottery loser, thus the reason why voltage wont give me any more mhz.
If you have a big OC with high voltage could be the cause for different temps.
As I said, your temps are high, but not so high that I immediately thing something is wrong. I have never used enough thermal paste to make on "X" on the die, so my best guess is you have used too much. I use the pea method and some people like the line method (never heard the rice grain analogy from above, but I like it). Your cooling system is more than adequate for one GPU and a CPU. It may be worth the trouble to reapply and use another method to see if you have better results.