If you can reduce that "700+GB" to below 450GB...then a cloning operation is possible.
Look long and deep as to what exactly is on that drive?
Old downloads you no longer need, multiple copies of things, games you no longer play, etc, etc.
Pare down that space.
Specific steps for a successful clone operation:
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Verify the actual used space on the current drive is significantly below the size of the new SSD
Download and install
Macrium Reflect (or Samsung Data Migration, if a Samsung SSD)
Power off
Disconnect ALL drives except the current C and the new SSD
Power up
Run the Macrium Reflect (or Samsung Data Migration)
Select ALL the partitions on the existing C drive
Click the 'Clone' button
Wait until it is done
When it finishes, power off
Disconnect ALL drives except for the new SSD
Swap the SATA cables around so that the new drive is connected to the same SATA port as the old drive
(ignore this step)
Power up, and verify the BIOS boot order
If good, continue the power up
It should boot from the new drive, just like the old drive.
Maybe reboot a time or two, just to make sure.
If it works, and it should, all is good.
Later, reconnect the old drive and wipe as necessary.
Delete the original boot partitions, here:
https://social.technet.microsoft.com/Forums/windows/en-US/4f1b84ac-b193-40e3-943a-f45d52e23685/cant-delete-extra-healthy-recovery-partitions-and-healthy-efi-system-partition?forum=w8itproinstall
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