Ah, that's not an 80 Plus Platinum, which explains the discrepancy in the cabling. This is the most basic 80 Plus certification, frequently referred to as 80 Plus White. Keep in mind through all of this is that this is a *really* old PSU, probably a decade old, and it's likely in its last stretch.
But I'm still confused by your cabling situation. Your problem isn't not having enough connections -- this PSU is outfitted to have two 6+2 and four 6-pin connections. From what you write, your problem appears to be not having enough *cables* which is a very different problem.
You talk about an 8-pin "for the power supply" but that's not how you determine a cable. Modular power cables are only standardized on the GPU side, there's no industry standard for pinouts on the PSU side, so it's not as simple as going out and finding some generic 8-pin-to-whatever cable and just plugging it in.
This is assuming I'm completely grasping what you're getting at here. Talking about the pins on the PCIE connector as the same as the pins on the power supply makes this all a bit confusing since they're not the same thing.
Your best bet is to go and get cables directly from Silverstone.
http://www.silverstonetek.com/product_access.php?tno=4&area=en
The good news is that Silverstone says that the cables are standardized across all their PSUs, though I still think it's worthwhile to double-check your model with customer support, simply because of its advanced age. Do not just buy any old PCIE cable that physically fits into the PSU because the wrong pinout gives a good chance for Very Bad Things to happen.
Though given the age of the PSU and the effort, time (and a bit of money) involved in replacing the cable, I'd be strongly tempted to just buy a new PSU with four 6+2 pin connectors and call it a day.
PCPartPicker part list /
Price breakdown by merchant
Power Supply: SeaSonic - FOCUS Plus Gold 750W 80+ Gold Certified Fully-Modular ATX Power Supply ($86.31 @ Amazon)
Total: $86.31
Prices include shipping, taxes, and discounts when available
Generated by PCPartPicker 2018-03-11 13:23 EDT-0400