It's really up to your own personal choice here.
If the loading times are really getting on your nerves and making you angry then go for the SSD, if you can live with the longer loading times an upgraded monitor is the obvious choice.
Of the two monitors I'd opt for the smaller Acer, 32" is really too large for a desktop display, unless you can sit at least 2 metres away.
I don't play Skyrim but have well over 100 hours total time on Wild Hunt and can say, with my hand on my heart, that it looks absolutely fabulous on my 27" 1440 Acer IPS screen ( similar to the one you have in mind, mine's 144Hz Freesync, though ).
So, I suggest you try to see monitors like those you are thinking about, or even 24" ones, actually working, speak to friends, neighbours, people at work or family members, maybe even look in on your local computer stores so you can see for yourself if the change is worth it to you.