With a VS, I'm going to assume you are not in US. That said, there's a good chance that that VS is actually one of the better budget psus available. You only need a decent 350w psu to run a gtx 950 and even bumping up to a gtx1060 will only increase that to 450w. So for a stock demand system, that VS is fine. Just don't try to overclock the cpu/gpu much if any, or that'll change demands, not just wattage output.
SLI with a 950 is pointless, you'll still have just 2Gb of vram, so the added capabilities (70% at absolute best, 0% worst) realistically won't be used. While the Corsair RMx750 is one of the best psus on the market, it's totally overkill for any system you put together short of sli 970's, which is pretty much beat up by a decent 1080 single card in a bunch of popular games.
The far cheaper RMx550w or Seasonic Focus Plus 550w would be a far better choice, it'll easily handle any OC you can put on that i5 and any single card less than a gtx1080ti. For amd gpus add 100w.