The random read speed of a ssd helps with loading the operating system into memory, but it doesn't help with initializing drivers and rendering display. At some point, the system clock affects load times much more than the speed of the drive, at which point halving latency might reduce load time by 0.1s rather than 30s.
In other cases, such as swap/page files or caching, the read/write speed and latency have a massive impact on the system. NVME has been useful specifically in cases where files are cached into a ssd in bursts and transferred to RAID arrays at a more constant rate, and vice versa. That's where we use something like an Intel Optane nvme.
As far as I am aware, MLC/TLC NVME drives in normal builds don't drastically improve...