Do NOT use the sensor inside the CPU chip to guide the case ventilation fans. It is ideal to guide the CPU chip cooler, but not the rest of your system. (There are a few cases in which one is forced to use the CPU chip sensor for case fans, but they are uncommon.) Most mobos actually do NOT have access to the temperature of any graphics card components (unless they use a non-standard design) so you normally do NOT have any option to use GPU temperature sensors for case fans.
Many mobos have more than one temperature sensor on the mobo. There is always a "general one" located and intended by the mobo maker to be the best representation of ALL the heat removal needs of mobo components. Extra sensors are intended for use IF you have extra fans mounted and directed at particular mobo component locations (say, the VRM or North Bridge). For those particular fans you can use the special-purpose sensors, but you still should have SOME fans for general case ventilation that use the "general" sensor.
Graphics cards most commonly have their own cooling fan systems and always do their own management of those fans to keep the card's components cooled. The never let the mobo take control of graphics card cooling, and hence normally do not send any temperature info to the mobo. Actually, there is no "standard" way to do that, although many graphics card makers send out their temp info on some contact in the PCIe socket and use their own software utilities to let you "see" that info. SOME graphics cards also include "standard" 4-pin fan sockets on them. These send out to any fan connected the same fan control signals used by the on-card fans to cool the card. Now, the on-card fan draws air from its immediate surroundings to cool the card components. So IF you mount a fan in your case side that draws in outside cool air and directs it toward the graphics card to aid in its cooling efforts, then power and control of that particular fan is best done from the fan output on the graphics card. But that is NOT intended to be used for general case cooling.