The reason 4 sticks of 400MHz ram run at 333MHz is because they are double sided sticks. If you use single sided sticks all four lanes will run at 400MHz. So, its perfectly okay to mix your PC4000 with PC3200.
But, I'm confused. You tag already says you have 1GB memory (2x512MB). It appears those are double sided sticks. Adding 2 more stick of 256MB each is going to cause you to drop back to PC2700 speed. Its okay to run your 2x512MB stick at whatever speed rating there at, but once you add the other, BOOM, 333MHz.
I don't know the technical reason for this, but Nvidia motherboard manuals clearly state this. So, to make a long story short...with AMD based motherboards, 1GB is sufficient if your going to run four slots of memory. Otherwise, the fall back in speed to PC2700 is greater than the benefits of the integrated memory controller on the Athlon64 chips. Your performance will actually receed instead of improving after adding the additional memory.
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