seems like your voltage is extremely high, that may have something to contribute to the problem. I'm also thinking that your thermal pase may not be applied correctly ,or your heat sink and fan may not be makin' full contact. What kind of flow do you have in your case ,what are ambient air temps, what is the heat sink and fan your using, and thermal paste your using? did you take the plastic sheet off of the bottom of the hsf?
By the way I did notice a huge jump from going to 3.2 from 2.1 as far as performance goes. 2000+ 3dmark 05 points and much better gameplay at 19x12. and I would assume that office apps ,dvd buring and what not would have increased also. but watch out for installing windows overclocked on raid 0 raptors ,because mine did not work until i set it back to optomized defaults, yet it is dual prime stable for days with no more than 49c...