Actually, I'm using 2 160GB SATA2 WD Enterprise drives. 7200RPM but every benchmark I've ran says I have better performance than any 15k drive and I'm almost as fast as 4x36GB Raptor drives in RAID-0. I'm doing roughly 115+mb/s with a seek-time of 8ms with my setup. Same with HDTach...I'm faster than older 74GB Raptors in RAID-0. I'm in no hurry to get the new Raptors right now.
Of course those are all synthetic benchmarks. I'm sure you'll notice a difference with 10k drives in a real-world situation...maybe
I've never tried 10K drives in RAID-0 but I'd like to
Realstically though, if a 10s boot-time is too long for you and you can't stand waiting 3s to load the next dungeon, then yeah get a couple 10k drives. But that's the only time you'll ever notice it...when you're loading data that's not already in RAM. When I rack up enough cash I just might RAID some Raptors for system/page file to see if there's a big difference
You'll really only notice your hard-drives in the first 30 minutes or so of game-play. The rest of the time you're most likely pulling from RAM. I'd first put the cash in to something that will offer more overall performance for a longer period of time, i.e. a faster processor, more RAM, or a better video card.