C:\Windows\System32 folder every time I boot up

Hello guys, Whenever I turn on my pc using Windows XP home edition, a window pops up for the C:\Windows\Sytstem32 folder. I always close it and go on about my business but it is really getting annoying. I know it has to do with my registry, I have tried the quick fix, xp_system32opens.vbs, and it tells me the script could not fix my issue. The expected registry value was not found. I want to manually do it but I really dont know what I'm doing and dont want to screw things up here. I have opened regedit and have an HKLM and HKCU text file, I do not know where to go from here. I would greatly appreciate if someone can help shed some more light on this for me. Should I copy and paste those two text files in here?