Need help clarifying which cables to use?

I am buying all the parts to my system and am stuck on the psu. My system should roughly look like this
p965 ds3
8800gts 320
Samsung Spintpoint T 500GB SATA
2x1 gb ocz vindicator ddr2 800 ram
and i am going to get the OCZ StealthXStream OCZ600SXS ATX12V / EPS12V 600W Power Supply.
it has 4 12v rails, i wanted to know does it matter which rail i connect for lets say my cpu, gpu and motherboard etc.
or am i getting this all terribly confused?
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More about need clarifying cables
  1. dont quote me but i know the OCZ gamextreme 700W has a sticker on the PSU telling you what rails are which & what to plug in
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