Yes, as I said, use a multimeter as it is more accurate the software and BIOS. If the readings are accurate, you might want to get rid of the PSU as soon as possible as 14.5v on the 12v line is most likely going to damage something. Power supplies are as much quality as the wattage of the unit itself, so next time go for something from a good manufacturer like Seasonic, Corsair, Antec or Silverstone for example.