Overclocking before windows installation or after?

My first post and probably a dumb one too.
I am getting my new board, and cpu tomorrow.
Amd 5000+ black edition.
Since i am getting a new board i am going to reinstall windows.
My question is
should i be overclocking cpu before i install windows or after i install one?
Does it even metter?
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More about overclocking windows installation after
  1. might wanna do it after
  2. wow that was fast.
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