I'd consider further optimization of your current setup before spending that kind of money on another x2 and depending on scaling of quad GPU. There are articles showing that the returns for multi GPU scaling are the highest at 3 GPUs. I think with your current setup you should be able to get acceptable performance at 16x10. Make sure your OS is running as lean as possible and that you are using the latest BIOS for your board, as well as the latest motherboard and video card drivers.
Also, there is a lot to be said for fine tuning your video card settings in CCC or ATI Tray tools. As well, tweaking settings in your games can have HUGE returns on performance. Too often people put every possible setting to the maximum possible value (16x MSAA and 32x AF will cripple any card or cards). You need have the patience and initiative to play with each and every setting. Find a baseline, like every setting the same (ie every setting medium, or every setting high). Keep a record of your frame rates over a period of time, through different situations (sitting still w/ little action, or running around in mayhem). Once you've established a baseline to compare against, begin playing with one setting at a time. Increase or decrease the setting and note its effect on your framerate vs. its effect on visual quality. You want to find what has the highest effect on framerate with the smallest effect on visual quality. A lot of times there are settings that have huge effects on framerates between on or two increments and little to no effect on visual quality.
As I've said, this will take time and is an arduous process, but the reward is well worth it. Fully tweaking every setting can give you performance you never thought possible while retaining spectacular visual quality. It's all a question of motivation and patience.