im just an amatuer, but i think that windows vista 32 bit only recognized 3 gb memory, so there is no point in having 4 unless you get 64 bit. you better double check this tho, as i may be wrong =p
ive heard abit mobo is better than asus
a lot of people recommend your case, so your fine there. also your processor is great.
I would get 2x2gb memory so you have the option to upgrade 8gb if you ever needed to do that, also the XIGMATEK HDT-S1283 120mm Rifle CPU Cooler on newegg is only $37 and is the highest rated cpu cooler on frostytech.com, so I would get that