Doing 5x 20Gb partitions in RAID 0 and the rest as RAID 5 doesn't make much sense; if one fails, you lose everything on the RAID 0 array, and the rest is left fine.
Technologically; its inefficient since you'd be partitioning the drives and THEN making RAID arrays from that; you would be much better off doing one big RAID 5 array; it would probably perform faster than 5x20GB partitions in RAID 0, not to mention that all your data would be backed up - you'd get 4TB of storage, which is a ton anyways.