I've been upgrading, building my own PC, and testing different old version PC's, and based on my experience I have found out that, by design, CPU's have limited RAM they can handle. The additional memory can be recognized as extended memory, but for some reason is not part of the CPU's workig memory. Probably it might need additional software (driver) to use it, which means a challenge for computer systems programmers. Trying software as DETECTIVE DRIVER, GENIOUS DRIVER, or so, is a good test to do.
Basically, before adding memory, we can go to internet, write the CPU's brand name, then we know the maximum RAM it can handle. Also cross information with the motherboard in use, which also relates to the CPU in use, and the maximum RAM the motherboard is designed.
Support websites to build PC's recommend to start Selecting the CPU that meet your needs, and automatically you can select the motherboard and RAM you need. The motherboard can vary from a basic to and advanced, depending on your needs.
Find the links related to HOW TO BUILD MY OWN PC, then you're going to get first class in formation.
If you don't need the extra memory, you can easily sell it through websites as ebay.com, PC shops, or keep it as spare parts. Remove it from your computer to avoid aging.
I hope my friend this could help you, and keep your practice upgrading computers. It's really fun.
Have a nice day.