Dual monitor setup while gaming

Greetings,

Allo everyone, I've had a dual monitor setup for awhile now and hardly ever use my second monitor for well.... anything. My main monitor is a samsung 22 inch and my second is a sharp aquos 32 inch tv. Current video card is an nvidia gtx 260 and I have an hdmi to dvi hooking up the card to the tv.

Now, is there any way that I can launch a game and have it use my second monitor (the t.v.) as a primary monitor without having to go into my display settings and make my primary monitor the t.v? I have gone through the nvidia desktop manager to see if there is anything that will allow me to do this, but I couldn't come up with anything. A friend of mine suggested trying a program called ultramon. It has a setting when you right click on the games launcher, you can customize it to open up on "second monitor." I have tried this with a few different games on my pc and none of them seem to work. I get a little blip of sorts on the second monitor but the game ultimately just starts on the primary one. Thanks in advance for any help!