memory speed might help you a little, what you might find helpful is faster swap space, or upgrading to a 64bit OS, and then more memory, but this obviously goes way beyond the $50 budget.
TBH I'm not sure where'll you'll get benefit, perhaps buying the 4Gb so that you can later go to 64bit, or even buying 2x2Gb in readiness, but you'll see virtually nothing until you can access it.
Thinking further about it though, the extra 0.4Gb will be an extra 25% of memory available to you, and probably more like an extra 35-45% available spare (above and beyond windows base load) so you might actually see some improvement.
One thing to remember is that vista superfetches everything it thinks you might need into ram, and then dumps it when you want something else, so RAM always looks very highly utilised, what is more important is how much WoW is using and how much of that is in swap file, if WoW is using 1Gb and none in swap, then there is little to be gained, if it is using 1Gb with 1Gb in swap then there might be somewhere to go.